Preparation, Characterization, and Enhanced Thermal and Mechanical Properties of Epoxy-Titania Composites

نویسندگان

  • Zakya Rubab
  • Adeel Afzal
  • Humaira M Siddiqi
  • Shaukat Saeed
چکیده

This paper presents the synthesis and thermal and mechanical properties of epoxy-titania composites. First, submicron titania particles are prepared via surfactant-free sol-gel method using TiCl₄ as precursor. These particles are subsequently used as inorganic fillers (or reinforcement) for thermally cured epoxy polymers. Epoxy-titania composites are prepared via mechanical mixing of titania particles with liquid epoxy resin and subsequently curing the mixture with an aliphatic diamine. The amount of titania particles integrated into epoxy matrix is varied between 2.5 and 10.0 wt.% to investigate the effect of sub-micron titania particles on thermal and mechanical properties of epoxy-titania composites. These composites are characterized by X-ray photoelectron (XPS) spectroscopy, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric (TG), and mechanical analyses. It is found that sub-micron titania particles significantly enhance the glass transition temperature (>6.7%), thermal oxidative stability (>12.0%), tensile strength (>21.8%), and Young's modulus (>16.8%) of epoxy polymers. Epoxy-titania composites with 5.0 wt.% sub-micron titania particles perform best at elevated temperatures as well as under high stress.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preparation and characterization of Epoxy/Lead oxide nano-composite for shield against gamma and X-rays

Polymer nano-composites are a group of materials that represent proper mechanical, chemical, thermal and optical properties due to the presence of certain percentages of a filler in a polymeric matrix. In this study lead oxide nanoparticles were prepared by direct precipitation method. Then the lead oxide-epoxy resin nanocomposite was prepared by mixing (without solvent) with different weight p...

متن کامل

An experimental investigation of novel hybrid epoxy/glass fibers nanocomposite reinforced with nanoclay with enhanced properties for low velocity impact test

The application of nanoparticles in order to enhance the composites properties has been recently attracted many researchers' attentions. To increase the mechanical and physical properties of the composites, the nanoparticles have no significant effect on the weight and nanostructure of composites. One of the well-known nanoparticles is the Nanoclay (NC) that have been widely used in industries ...

متن کامل

Experimental Study on Amine-Functionalized Carbon Nanotubes’ Effect on the Thermomechanical Properties of CNT/Epoxy Nano-composites

This paper investigated the effect of the amine-functionalized carbon nanotubes (CNTs) on the thermomechanical properties of CNT/epoxy nanocomposites. Mechanical stirring and ultra-sonication were utilized to uniformly disperse CNTs into the epoxy matrix. Non-functionalized and amine-functionalized CNTs with different weight percentages (wt. %) were mixed into the epoxy resin. Using standard te...

متن کامل

MECHANICAL CHARACTERIZATION AND ANALYSIS OF RANDOMLY DISTRIBUTED SHORT BANANA FIBER REINFORCED EPOXY COMPOSITES

Short banana fiber reinforced composites have been prepared in laboratory to determine mechanical properties. It has been observed that as soon as the percentage of the banana fiber increases slightly there is a tremendous increase in ultimate tensile strength, % of strain and young modulus of elasticity. Reinforcement of banana fibers in epoxy resin increases stiffness and decreases damping pr...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 2014  شماره 

صفحات  -

تاریخ انتشار 2014